You may complete up to 25 daily quests per day per character. The exact reset hour depends on the realm, but it never changes, is chosen to be in the early AM, and will not coincide with the instance reset. You can double-check by mousing over the daily quests completed out of 25 in the upper-right corner of your quest log. Prior to Patch 2.4 there was a limit of 10 daily quests per day, but was increased to the current limit to accommodate the large number of Shattered Sun Offensive daily quests.
Often, a quest chain needs to be completed first to unlock the quest.
[72] 
[71] 
[74P] 
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